Researchers at the University of Waterloo have developed a novel magnesium-based electrolyte, paving the way for more sustainable and cost-effective batteries for electric vehicles (EVs) and renewable energy storage.
1. Introduction Rechargeable magnesium batteries (RMBs) have attracted great interest in energy storage research due to the advantages of magnesium (Mg) metal, including rich crustal content (the sixth abundant metal element), high volumetric capacity (3833 mAh cm −3), low potential (−2.37 V), and less prone to dendrite formation, , .
Why do we need a magnesium battery?
Magnesium enables dendrite-free operation, improving battery safety and lifespan. New cathodes and electrolytes address issues like Mg²⁺ diffusion and anode passivation. Mg batteries suit EVs, grid storage, aerospace, and portable devices due to low cost. AI and materials engineering may speed up Mg battery commercialization and research.
Magnesium batteries offer ~3833 mAh/cm³ capacity, nearly twice that of lithium-ion batteries. Magnesium enables dendrite-free operation, improving battery safety and lifespan. New cathodes and electrolytes address issues like Mg²⁺ diffusion and anode passivation. Mg batteries suit EVs, grid storage, aerospace, and portable devices due to low cost.
How do rechargeable magnesium batteries work?
Rechargeable magnesium batteries (RMBs) operate via the reversible migration of Mg 2+ ions between the anode and cathode through an electrolyte medium. RMBs are broadly categorized into aqueous and non-aqueous systems based on the solvent type used in the electrolyte.
Could magnesium batteries power EVs?
With relatively low costs and a more robust supply chain than conventional lithium-ion batteries, magnesium batteries could power EVs and unlock more utility-scale energy storage, helping to shepherd more wind and solar energy into the grid. That depends on whether or not researchers can pick apart some of the technology obstacles in the way.
Energy density and power Rechargeable magnesium batteries (RMBs) excel in volumetric energy density; for instance, MgFeSiO 4 cathodes deliver over 300 mAh/g at 2.4 V vs. Mg/Mg 2+ (at 1C and 25 °C), yielding an energy density of 720 Wh/L, comparable to the 700 Wh/L of commercial lithium-ion batteries (LIBs) [55, 105].